Enhancing Ionic Conductivity of Carboxymethyl Cellulose-Lithium Perchlorate with Crosslinked Citric Acid as Solid Polymer Electrolytes for Lithium Polymer Batteries

نویسندگان

چکیده

Lithium batteries development are triggered so many efforts in producing electronic devices due to its excellent performance as energy storage systems. One of the appealing points solid polymer electrolytes for developing solid-state lithium batteries. In this study, Solid with crosslinked treatment (SPE-C) were prepared from carboxymethyl cellulose-lithium perchlorate (CMC-LiClO4) and citric acid (CA) a crosslinker via solution casting method. All SPE-C membranes assembled into battery coin cells. Degree degradation measured observe crosslink formation confirmed by fourier transform infrared (FTIR), whereas cells characterized electrochemical impedance spectroscopy (EIS) linear sweep voltammograms (LSV). The results showed that process is successfully obtained C=O ester linkage CA vibration within COO- CMC crosslinking bond formation. effect also contributed on enhancing ionic conductivities EIS results. highest conductivity was SPE-C2 (1.24×10-7 S/cm) electrochemically stable 2.15 V based LSV measurement. has good dielectric behavior than others high ions mobilities migration ion clusters formation, thus it would be useful further study obtaining powerful

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Polymer Electrolytes for Lithium/Sulfur Batteries

This review evaluates the characteristics and advantages of employing polymer electrolytes in lithium/sulfur (Li/S) batteries. The main highlights of this study constitute detailed information on the advanced developments for solid polymer electrolytes and gel polymer electrolytes, used in the lithium/sulfur battery. This includes an in-depth analysis conducted on the preparation and electroche...

متن کامل

Characterization of Lithium-based Solid Polymer Electrolytes

Sol-gel derived poly(oxyethylene)/siloxane hybrids doped with lithium hexafluoroantimonate, LiSbF6, have been prepared. Compositions of these novel xerogel electrolytes were identified using the conventional d-U(2000)nLiSbF6 notation, (where n is the molar ratio of oxyethylene moieties per Li + ion) and samples with n between ∞ and 2.5 were characterized by conductivity measurements, cyclic vol...

متن کامل

Poly (acrylic acid sodium) grafted carboxymethyl cellulose as a high performance polymer binder for silicon anode in lithium ion batteries

The design of novel binder systems is required for the high capacity silicon (Si) anodes which usually undergo huge volume change during the charge/discharge cycling. Here, we introduce a poly (acrylic acid sodium)-grafted-carboxymethyl cellulose (NaPAA-g-CMC) copolymer as an excellent binder for Si anode in lithium ion batteries (LIBs). The NaPAA-g-CMC copolymer was prepared via a free radical...

متن کامل

All-Solid-State Lithium-Ion Batteries with Grafted Ceramic Nanoparticles Dispersed in Solid Polymer Electrolytes.

Lithium-based rechargeable batteries offer superior specific energy and power, and have enabled exponential growth in industries focused on small electronic devices. However, further increases in energy density, for example for electric transportation, face the challenge of harnessing the lithium metal as negative electrode instead of limited-capacity graphite and its heavy copper current colle...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: International Journal of Renewable Energy Development

سال: 2022

ISSN: ['2252-4940']

DOI: https://doi.org/10.14710/ijred.2022.40090